Anmol Chemicals is the pioneer manufacturers of Methyl anthranilate, Dimethyl anthranilate, Pharmaceutical Excipients Fragrance & Flavor chemicals in India. We offer Halal and Kosher Methyl anthranilate, Dimethyl anthranilate made in an ISO9001:2008, ISO22000:2005 (FSSC22000) and cGMP certified facility. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in UAE, Europe, Africa, USA, China and has several associated manufacturing facilities spread across India. All the Information on Physics, Chemistry, Applications, Uses and Technology on Manufacture of Methyl anthranilate, Dimethyl anthranilate is in these pages.
The units have one or more of the certifications like FDA GMP, ISO 9001, ISO 22000, HACCP, REACH, Kosher & Halal

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Methyl Anthranilate SDS GHS, MSDS Sheet

1. Product Identification

Synonyms: Methyl 2-aminobenzoate, Methyl 2-anthranilate
CAS No.: 134-20-3
EINECS: EC Number: 205-132-4
Molecular Weight: 151.16
Molecular Formula: C8H9NO2
Recommended usage: Industrial Manufacturing.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3

Labelling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Hazard statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary statements:
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352-IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xi Irritant R36/37/38
For the full text of the H-Statements & R-phrases mentioned in this Section, see Section 16.

OSHA Hazards: Not considered highly hazardous by OSHA.

3. Composition/Information on Ingredients

Ingredient: Methyl Anthranilate
CAS No.: 134-20-3
EINECS: EC Number: 205-132-4
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Combustible at high temperature..
Auto-Ignition Temperature: 530C (986F).
Flash Points: 104 deg C ( 219 deg F)
Flammable Limits: Not available.
Products of Combustion: Nitrogen oxides, Carbon dioxide, Carbon monoxide, fumes.
Fire: Flammable in the presence of open flame.
Explosion: Slightly explosive in presence of heat.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.

7. Handling and Storage

Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Methyl Anthranilate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not Established.
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Methyl Anthranilate is a yellowish solid or liquid melting/freezing at 24C.
Odor: It has typical floral odor.
Solubility: It is slightly soluble in water.
pH: NA
Density: 1.17 g/mL at 20C (68F)
Molecular Weight:
151.16
Molecular Formula: C8H9NO2
% Volatiles by volume @ 21C (70F): -
Boiling Point: 256°C (492.8°F)
Melting Point: 24°C (75.2°F)

10. Stability and Reactivity

Stability: Methyl Anthranilate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Oxides of Nitrogen, Carbon dioxide, Carbon monoxide & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, reducing agents, Acid anhydrides, chloroformates, acids, acid chlorides.
Conditions to Avoid: Incompatibles, heat & light.

11. Toxicological Information

Toxicity data
ORL-RAT LD50 2910 mg kg-1
ORL-MAM LD50 3900 mg kg-1
Carcinogenic Effects: Not know as carcinogen.

12. Ecological Information

Environmental Fate: Not available.
Environmental Toxicity: Not known. Toxicity to fish is expected.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are toxic.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

US DOT Classification: Not regulated
Canada TDG Classification: Not regulated
IATA: Not regulated
ADR/RID: Not regulated
IMDG:
Not regulated

15. Regulatory Information

USA:
OSHA Hazards
: Not considered highly hazardous by OSHA.
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Fire Hazard: -; Reactivity Hazard: -; Pressure Hazard: -; Immediate Health Hazard: Yes; Chronic Health Hazard: -
Massachusetts Right To Know Components: Not Listed
Pennsylvania Right To Know Components: Not Listed
New Jersey Right To Know Components: Not Listed
California prop. 65: Contains no chemical subject to California Prop 65.
TSCA: listed on the TSCA Inventory.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: None of the chemicals in this material have an RQ.
Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
WGK (Water Danger/Protection):
CAS# 134-20-3: 1

EINECS EC Number: 205-132-4
Hazard Symbols: Xi
Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/39 Wear suitable gloves and eye/face protection.

Canada - DSL/NDSL: CAS# 128-37-0: is listed on Canada's DSL List.
Canada - WHMIS
: CLASS D2B.
Canadian Ingredient Disclosure List: CAS# 134-20-3 is not listed on Canada's Ingredient Disclosure List.
Canadian Domestic Substance List (DSL) Inventory Listing: Listed on the DSL.
HMIS (Perceived): Health Hazard: 0, Fire Hazard: 1, Reactivity: 0, Personal Protection: E
NFPA (Perceived): Health: 0, Flammability: 1, Reactivity: 0

Section 16 - Additional Information

H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation.
Xi = Irritant
R36/37/38 Irritating to eyes, respiratory system and skin.

Disclaimer:
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Our company provides this Methyl Anthranilate SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Methyl anthranilate manufacturers:

Anmol Chemicals
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564. FAX: 91-22-23728264

e-mail: anmolc@mtnl.net.in

Anmol Chemicals

Exports to USA, Canada, UAE, Dubai, South Africa, Tanzania, Kenya, Nigeria, Egypt, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Europe Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Korea, Japan,etc.

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